Setting the Default Account in iOS Mail chooses the email account, whereas setting the Primary Alias in Microsoft determines the preferred Outlook sender address. These are two different settings.
iOS Mail app may not allow this, however you may attempt as per the steps given below.
If your existing Outlook account is already configured in iOS Mail:
- You do not need to add the new alias separately.
- Your new alias belongs to the same Microsoft account.
- You can use the existing account to receive messages sent to either alias.
- To send emails from the new alias, you may need to configure the From address in Outlook.com or the Outlook app.
My recommendation: If you want the new alias to be your principal email address for sending and receiving emails, first make it the primary alias in your Microsoft account, then check the default sender address in Apple Mail.
Ensure your new alias is the default sender
Since you have already made the new alias your primary Microsoft account alias:
- Microsoft uses the primary alias as the default From address for Outlook.com.
- Apple Mail may use the sender address supplied by the Microsoft account when composing messages.
- iOS Mail does not provide a separate permanent default-alias selector for an Outlook account.
Verify the sender address
- Open the Apple Mail app.
- Tap the Compose icon.
- Tap the Cc/Bcc field.
- Tap the From field.
- Check which email address is displayed.
If your new alias is displayed, you're all set.
If your old address is displayed and the new alias is not selectable, try composing a message using outlook.com --> Read this Send email from a different address in Outlook.com