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You seem to be wanting help with a Google app, is that right? This "save to device" doesn't seem to be from any Apple app?
So what is confusing to markwmsn, to Servant of Cats, and to me, all of us pretty experienced users, is the statement "i have some photos that are in the cloud that aren't on the device." We don't see how that can be true.
We are also unsure of the "save to device" command, and what it means. Mostly, if a web site, for instance, has you save a picture, it goes into the Photos Library (again, not into the app.) Then Photos takes over, doing what we've discussed, with the local Library and the Library at iCloud.com.
As far as pictures that you've backed up to your computer, there's no way that Photos would keep track of that backup. The computer backup does, though. If I wanted to collect the pictures that hadn't been backed up, I'd use the date and time of the backup. I would sort pictures on the iPad in order of date added, and select the pictures before or after the backup date.